TY - JOUR
T1 - Thermal effects on the structure and relaxation properties of poly(monocyclopentyl itaconate)
AU - Calleja, Ricardo Díaz
AU - Sanchis, Maria‐Jesus ‐J
AU - Gargallo, Ligia
AU - Radíc, Deodato
PY - 1995/11
Y1 - 1995/11
N2 - The effect of thermal treatment and subsequent chemical structural modifications on the viscoelastic and dielectric properties of PMCPI (poly(monocyclopentyl itaconate)) was studied. The low temperature relaxation (γ‐relaxation) is unaffected by the thermal history or chemical modifications. The intermediate relaxation (β‐relaxation) is shifted by about 40°C to higher temperature after thermal treatment. The α‐relaxation (related to the glass transition temperature Tg) suffers more striking changes when moving to higher temperatures.
AB - The effect of thermal treatment and subsequent chemical structural modifications on the viscoelastic and dielectric properties of PMCPI (poly(monocyclopentyl itaconate)) was studied. The low temperature relaxation (γ‐relaxation) is unaffected by the thermal history or chemical modifications. The intermediate relaxation (β‐relaxation) is shifted by about 40°C to higher temperature after thermal treatment. The α‐relaxation (related to the glass transition temperature Tg) suffers more striking changes when moving to higher temperatures.
UR - https://www.scopus.com/pages/publications/26144475670
U2 - 10.1002/macp.1995.021961129
DO - 10.1002/macp.1995.021961129
M3 - Article
AN - SCOPUS:26144475670
SN - 1022-1352
VL - 196
SP - 3789
EP - 3796
JO - Macromolecular Chemistry and Physics
JF - Macromolecular Chemistry and Physics
IS - 11
ER -