Synthesis, solution properties, and chain flexibility of poly (methyl dodecyl itaconate)

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Resumen

The dilute solution behavior of poly (methyl dodecyl itaconate) (PMeDoI) has been studied in THF and n-butanol at 298 K, by intrinsic viscosity, light scattering, and size-exclusion chromatography (SEC) measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The flexibility factors σ and C∞ and the thermodynamic parameters B were calculated using the Stockmayer-Fixman equation. The A2 and the B values are indicative of the presence of the excluded volume effect. The results obtained are com-.

Idioma originalInglés
Páginas (desde-hasta)351-359
Número de páginas9
PublicaciónJournal of Macromolecular Science - Physics
Volumen29
N.º4
DOI
EstadoPublicada - 1 dic. 1990
Publicado de forma externa

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