TY - JOUR
T1 - Synthesis and characterization of bulky side chain methacrylate polymers
AU - Radić, Deodato
AU - Martínez, Francisco
AU - Gargallo, Ligia
AU - Hamidi, Nasrollah
PY - 1996
Y1 - 1996
N2 - The synthesis, and dilute solution behavior of poly(2,4-dimethylphenyl methacrylate) (2,4DMP), poly(2,5-dimethylphenyl methacrylate) (2,5DMP), and poly(3,5-dimethylphenyl methacrylate) (3,5DMP) is described. Comparison is made with results reported for other bulky side chain polymers. The Kuhn-Mark-Houwink-Sakurada (KMHS) relationships were established. The unperturbed dimensions (r2)o1/2. the rigidity factor σ, the characteristic ratio C∞ and the thermodynamic parameters were determined, using the Stockmayer-Fixman equation, from viscometric data in good solvents. The high rigidity observed for these polymers is explained assuming that these polymers behave as kinked-chains.
AB - The synthesis, and dilute solution behavior of poly(2,4-dimethylphenyl methacrylate) (2,4DMP), poly(2,5-dimethylphenyl methacrylate) (2,5DMP), and poly(3,5-dimethylphenyl methacrylate) (3,5DMP) is described. Comparison is made with results reported for other bulky side chain polymers. The Kuhn-Mark-Houwink-Sakurada (KMHS) relationships were established. The unperturbed dimensions (r2)o1/2. the rigidity factor σ, the characteristic ratio C∞ and the thermodynamic parameters were determined, using the Stockmayer-Fixman equation, from viscometric data in good solvents. The high rigidity observed for these polymers is explained assuming that these polymers behave as kinked-chains.
UR - https://www.scopus.com/pages/publications/0029776940
U2 - 10.1002/pen.10401
DO - 10.1002/pen.10401
M3 - Article
AN - SCOPUS:0029776940
SN - 0032-3888
VL - 36
SP - 188
EP - 193
JO - Polymer Engineering and Science
JF - Polymer Engineering and Science
IS - 2
ER -