Properties of polyelectrolytes: Maleic acid-vinylpyrrolidone copolymers-2. Potentiometric behaviour in dilute solution

H. Ríos; L. Gargallo; D. Radić

doi:10.1016/0014-3057(85)90212-5

Properties of polyelectrolytes: Maleic acid-vinylpyrrolidone copolymers-2. Potentiometric behaviour in dilute solution

H. Ríos
, L. Gargallo
, D. Radić

Pontificia Universidad Católica de Chile

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

8 Citas (Scopus)

Resumen

The potentiometric behaviour of maleic acid-vinylpyrrolidone copolymer p(MA-co-VP) was studied as a function of added (1:1) electrolyte. The copolymer composition as well as the first and second intrinsic ionization values pK₀ were determined. The values of pK₀¹, pK₀² and ΔG⁰ (the standard electrostatic and conformational free energy change) were found to depend on the ionic strength. Also it was found that ΔG⁰ approaches a constant value when the added electrolyte concentration exceeded 0.5 M and the polyacid behaves like its monomeric analogue.

Idioma original	Inglés
Páginas (desde-hasta)	1045-1049
Número de páginas	5
Publicación	European Polymer Journal
Volumen	21
N.º	12
DOI	https://doi.org/10.1016/0014-3057(85)90212-5
Estado	Publicada - 1985
Publicado de forma externa	Sí

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title = "Properties of polyelectrolytes: Maleic acid-vinylpyrrolidone copolymers-2. Potentiometric behaviour in dilute solution",

abstract = "The potentiometric behaviour of maleic acid-vinylpyrrolidone copolymer p(MA-co-VP) was studied as a function of added (1:1) electrolyte. The copolymer composition as well as the first and second intrinsic ionization values pK0 were determined. The values of pK01, pK02 and ΔG0 (the standard electrostatic and conformational free energy change) were found to depend on the ionic strength. Also it was found that ΔG0 approaches a constant value when the added electrolyte concentration exceeded 0.5 M and the polyacid behaves like its monomeric analogue.",

author = "H. R{\'i}os and L. Gargallo and D. Radi{\'c}",

year = "1985",

doi = "10.1016/0014-3057(85)90212-5",

language = "English",

volume = "21",

pages = "1045--1049",

journal = "European Polymer Journal",

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T1 - Properties of polyelectrolytes

T2 - Maleic acid-vinylpyrrolidone copolymers-2. Potentiometric behaviour in dilute solution

AU - Ríos, H.

AU - Gargallo, L.

AU - Radić, D.

PY - 1985

Y1 - 1985

N2 - The potentiometric behaviour of maleic acid-vinylpyrrolidone copolymer p(MA-co-VP) was studied as a function of added (1:1) electrolyte. The copolymer composition as well as the first and second intrinsic ionization values pK0 were determined. The values of pK01, pK02 and ΔG0 (the standard electrostatic and conformational free energy change) were found to depend on the ionic strength. Also it was found that ΔG0 approaches a constant value when the added electrolyte concentration exceeded 0.5 M and the polyacid behaves like its monomeric analogue.

AB - The potentiometric behaviour of maleic acid-vinylpyrrolidone copolymer p(MA-co-VP) was studied as a function of added (1:1) electrolyte. The copolymer composition as well as the first and second intrinsic ionization values pK0 were determined. The values of pK01, pK02 and ΔG0 (the standard electrostatic and conformational free energy change) were found to depend on the ionic strength. Also it was found that ΔG0 approaches a constant value when the added electrolyte concentration exceeded 0.5 M and the polyacid behaves like its monomeric analogue.

UR - https://www.scopus.com/pages/publications/0005120045

U2 - 10.1016/0014-3057(85)90212-5

DO - 10.1016/0014-3057(85)90212-5

M3 - Article

AN - SCOPUS:0005120045

SN - 0014-3057

VL - 21

SP - 1045

EP - 1049

JO - European Polymer Journal

JF - European Polymer Journal

IS - 12

ER -

Properties of polyelectrolytes: Maleic acid-vinylpyrrolidone copolymers-2. Potentiometric behaviour in dilute solution

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