Poly(complexes) stabilized by acid-base interactions: Poly(4-vinylpyridine) and poly(ethylene-co-maleic acid)

V. Villar; A. Opazo; L. Gargallo; D. Radić; H. Rios; E. Clavijo

doi:10.1080/10236669808009721

Poly(complexes) stabilized by acid-base interactions: Poly(4-vinylpyridine) and poly(ethylene-co-maleic acid)

V. Villar
, A. Opazo
, L. Gargallo
, D. Radić
, H. Rios
, E. Clavijo

Pontificia Universidad Católica de Chile
Universidad de Chile

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

3 Citas (Scopus)

Resumen

Interpolymer complex (IC) formation between poly(ethylene-co-maleic acid) and poly(4-vinylpiridine) (P4VPy) has been observed and characterized. Data from viscosity, infrared spectroscopy and thermogravimetric analysis show the presence of an interpolymer complex depending on the composition and pH of the solution. The driving force for poly(complex) formation seems to be the specific acid-base interactions between free carboxylic groups of the copolymer and the pyridine nitrogen of P4VPy.

Idioma original	Inglés
Páginas (desde-hasta)	333-343
Número de páginas	11
Publicación	International Journal of Polymer Analysis and Characterization
Volumen	4
N.º	4
DOI	https://doi.org/10.1080/10236669808009721
Estado	Publicada - 1998
Publicado de forma externa	Sí

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@article{c93d519d7843402394bce155592c9cdb,

title = "Poly(complexes) stabilized by acid-base interactions: Poly(4-vinylpyridine) and poly(ethylene-co-maleic acid)",

abstract = "Interpolymer complex (IC) formation between poly(ethylene-co-maleic acid) and poly(4-vinylpiridine) (P4VPy) has been observed and characterized. Data from viscosity, infrared spectroscopy and thermogravimetric analysis show the presence of an interpolymer complex depending on the composition and pH of the solution. The driving force for poly(complex) formation seems to be the specific acid-base interactions between free carboxylic groups of the copolymer and the pyridine nitrogen of P4VPy.",

keywords = "Fourier-transform infrared, Gain in viscosity, Hydrogen-bond formation, Interpolymer complex, Poly(4-vinylpyridine), Poly(ethylene-co-maleic acid), Thermogravimetric analysis",

author = "V. Villar and A. Opazo and L. Gargallo and D. Radi{\'c} and H. Rios and E. Clavijo",

year = "1998",

doi = "10.1080/10236669808009721",

language = "English",

volume = "4",

pages = "333--343",

journal = "International Journal of Polymer Analysis and Characterization",

issn = "1023-666X",

number = "4",

}

TY - JOUR

T1 - Poly(complexes) stabilized by acid-base interactions

T2 - Poly(4-vinylpyridine) and poly(ethylene-co-maleic acid)

AU - Villar, V.

AU - Opazo, A.

AU - Gargallo, L.

AU - Radić, D.

AU - Rios, H.

AU - Clavijo, E.

PY - 1998

Y1 - 1998

N2 - Interpolymer complex (IC) formation between poly(ethylene-co-maleic acid) and poly(4-vinylpiridine) (P4VPy) has been observed and characterized. Data from viscosity, infrared spectroscopy and thermogravimetric analysis show the presence of an interpolymer complex depending on the composition and pH of the solution. The driving force for poly(complex) formation seems to be the specific acid-base interactions between free carboxylic groups of the copolymer and the pyridine nitrogen of P4VPy.

AB - Interpolymer complex (IC) formation between poly(ethylene-co-maleic acid) and poly(4-vinylpiridine) (P4VPy) has been observed and characterized. Data from viscosity, infrared spectroscopy and thermogravimetric analysis show the presence of an interpolymer complex depending on the composition and pH of the solution. The driving force for poly(complex) formation seems to be the specific acid-base interactions between free carboxylic groups of the copolymer and the pyridine nitrogen of P4VPy.

KW - Fourier-transform infrared

KW - Gain in viscosity

KW - Hydrogen-bond formation

KW - Interpolymer complex

KW - Poly(4-vinylpyridine)

KW - Poly(ethylene-co-maleic acid)

KW - Thermogravimetric analysis

UR - https://www.scopus.com/pages/publications/0032238512

U2 - 10.1080/10236669808009721

DO - 10.1080/10236669808009721

M3 - Article

AN - SCOPUS:0032238512

SN - 1023-666X

VL - 4

SP - 333

EP - 343

JO - International Journal of Polymer Analysis and Characterization

JF - International Journal of Polymer Analysis and Characterization

IS - 4

ER -

Poly(complexes) stabilized by acid-base interactions: Poly(4-vinylpyridine) and poly(ethylene-co-maleic acid)

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