TY - JOUR
T1 - Optimizing dispersion of torrefied spent coffee grounds for enhanced biochar-EVA composite properties through sodium percarbonate-assisted treatment
AU - Lee, Kuan Ting
AU - Gabriela, Situmorang
AU - Chen, Wei Hsin
AU - Rajendran, Saravanan
AU - Selvarajoo, Anurita
N1 - Publisher Copyright:
© 2025 The Korean Society of Industrial and Engineering Chemistry
PY - 2025/10/25
Y1 - 2025/10/25
N2 - This study aims to optimize biochar by combining 10 % sodium percarbonate with 90 % spent coffee grounds and torrefying at 300 °C for 30 min. Biochar enhances black color dispersion in a composite when blending the optimal biochar and ethylene vinyl acetate. The maximum carbon content of the optimal biochar is 59.97 %, exhibiting similar dispersion, packing density, pore size, and contact angle to carbon black. The optimal biochar's specific surface area and total pore volume are 7.12 m2·g−1 and 0.0018 cm3·g−1, respectively, 2.9 times and 1.2 times that of untreated torrefied spent coffee grounds with SP treated. The mechanical properties of the composite, which is blended with 15 wt% of the optimal biochar to ethylene vinyl acetate through trade-off analysis, indicate a tensile strength and Young's modulus of 1.03 MPa and 9.69 MPa, respectively. As the amount of blended optimal biochar increases, the tensile strength decreases while Young's modulus increases. Compared with a composite blended with the same 15 wt% of carbon black, the tensile strength and Young's modulus are 0.77 MPa and 9.55 MPa, respectively. In conclusion, the optimal biochar is a potential alternative material that could replace carbon black. This finding aligns with the developmental direction of achieving negative carbon emissions, promoting a circular economy and valorizing waste.
AB - This study aims to optimize biochar by combining 10 % sodium percarbonate with 90 % spent coffee grounds and torrefying at 300 °C for 30 min. Biochar enhances black color dispersion in a composite when blending the optimal biochar and ethylene vinyl acetate. The maximum carbon content of the optimal biochar is 59.97 %, exhibiting similar dispersion, packing density, pore size, and contact angle to carbon black. The optimal biochar's specific surface area and total pore volume are 7.12 m2·g−1 and 0.0018 cm3·g−1, respectively, 2.9 times and 1.2 times that of untreated torrefied spent coffee grounds with SP treated. The mechanical properties of the composite, which is blended with 15 wt% of the optimal biochar to ethylene vinyl acetate through trade-off analysis, indicate a tensile strength and Young's modulus of 1.03 MPa and 9.69 MPa, respectively. As the amount of blended optimal biochar increases, the tensile strength decreases while Young's modulus increases. Compared with a composite blended with the same 15 wt% of carbon black, the tensile strength and Young's modulus are 0.77 MPa and 9.55 MPa, respectively. In conclusion, the optimal biochar is a potential alternative material that could replace carbon black. This finding aligns with the developmental direction of achieving negative carbon emissions, promoting a circular economy and valorizing waste.
KW - Artificial neural network (ANN)
KW - Biochar
KW - Composite
KW - Ethylene vinyl acetate (EVA)
KW - Sodium percarbonate
KW - Spent coffee grounds (SCGs)
UR - https://www.scopus.com/pages/publications/105001503175
U2 - 10.1016/j.jiec.2025.03.042
DO - 10.1016/j.jiec.2025.03.042
M3 - Article
AN - SCOPUS:105001503175
SN - 1226-086X
VL - 150
SP - 758
EP - 770
JO - Journal of Industrial and Engineering Chemistry
JF - Journal of Industrial and Engineering Chemistry
ER -