Dielectric relaxations in poly(thiocarbonates)

The dielectric absorptions observed on six poly(thiocarbonates) (PTC) containing different substituents in the interphenylic carbon atom are subjected to a study. The α relaxation process associated with the glass transition temperature, which appears at the highest temperature studied, is overlapped with a strong conductive component. Between 80 and 100°C dielectric activity (β) is observed, which is related to structural relaxation phenomena. Polymers with double substitution on the interphenylic carbon atom show a γ relaxation with an activation energy of ca. 11 kcal mol⁻¹ while those where the carbon atom is linked to a cyclohexyl group show higher activation energies and their respective characteristics. A cryogenic absorption around −120°C, for at least three polymers with an activation energy of about 5 kcal mol⁻¹, is detected. © 1994 John Wiley & Sons, Inc.