Thermal effects on the structure and relaxation properties of poly(monocyclopentyl itaconate)

Ricardo Díaz Calleja; Maria‐Jesus ‐J Sanchis; Ligia Gargallo; Deodato Radíc

doi:10.1002/macp.1995.021961129

Thermal effects on the structure and relaxation properties of poly(monocyclopentyl itaconate)

Ricardo Díaz Calleja
, Maria‐Jesus ‐J Sanchis
, Ligia Gargallo
, Deodato Radíc

Polytechnic University of Valencia
Pontificia Universidad Católica de Chile

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The effect of thermal treatment and subsequent chemical structural modifications on the viscoelastic and dielectric properties of PMCPI (poly(monocyclopentyl itaconate)) was studied. The low temperature relaxation (γ‐relaxation) is unaffected by the thermal history or chemical modifications. The intermediate relaxation (β‐relaxation) is shifted by about 40°C to higher temperature after thermal treatment. The α‐relaxation (related to the glass transition temperature T_g) suffers more striking changes when moving to higher temperatures.

Original language	English
Pages (from-to)	3789-3796
Number of pages	8
Journal	Macromolecular Chemistry and Physics
Volume	196
Issue number	11
DOIs	https://doi.org/10.1002/macp.1995.021961129
State	Published - Nov 1995
Externally published	Yes

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title = "Thermal effects on the structure and relaxation properties of poly(monocyclopentyl itaconate)",

abstract = "The effect of thermal treatment and subsequent chemical structural modifications on the viscoelastic and dielectric properties of PMCPI (poly(monocyclopentyl itaconate)) was studied. The low temperature relaxation (γ‐relaxation) is unaffected by the thermal history or chemical modifications. The intermediate relaxation (β‐relaxation) is shifted by about 40°C to higher temperature after thermal treatment. The α‐relaxation (related to the glass transition temperature Tg) suffers more striking changes when moving to higher temperatures.",

author = "Calleja, \{Ricardo D{\'i}az\} and Sanchis, \{Maria‐Jesus ‐J\} and Ligia Gargallo and Deodato Rad{\'i}c",

year = "1995",

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doi = "10.1002/macp.1995.021961129",

language = "English",

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pages = "3789--3796",

journal = "Macromolecular Chemistry and Physics",

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T1 - Thermal effects on the structure and relaxation properties of poly(monocyclopentyl itaconate)

AU - Calleja, Ricardo Díaz

AU - Sanchis, Maria‐Jesus ‐J

AU - Gargallo, Ligia

AU - Radíc, Deodato

PY - 1995/11

Y1 - 1995/11

N2 - The effect of thermal treatment and subsequent chemical structural modifications on the viscoelastic and dielectric properties of PMCPI (poly(monocyclopentyl itaconate)) was studied. The low temperature relaxation (γ‐relaxation) is unaffected by the thermal history or chemical modifications. The intermediate relaxation (β‐relaxation) is shifted by about 40°C to higher temperature after thermal treatment. The α‐relaxation (related to the glass transition temperature Tg) suffers more striking changes when moving to higher temperatures.

AB - The effect of thermal treatment and subsequent chemical structural modifications on the viscoelastic and dielectric properties of PMCPI (poly(monocyclopentyl itaconate)) was studied. The low temperature relaxation (γ‐relaxation) is unaffected by the thermal history or chemical modifications. The intermediate relaxation (β‐relaxation) is shifted by about 40°C to higher temperature after thermal treatment. The α‐relaxation (related to the glass transition temperature Tg) suffers more striking changes when moving to higher temperatures.

UR - https://www.scopus.com/pages/publications/26144475670

U2 - 10.1002/macp.1995.021961129

DO - 10.1002/macp.1995.021961129

M3 - Article

AN - SCOPUS:26144475670

SN - 1022-1352

VL - 196

SP - 3789

EP - 3796

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 11

ER -

Thermal effects on the structure and relaxation properties of poly(monocyclopentyl itaconate)

Abstract

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