Synthesis, solution properties and chain flexibility of poly(2-thiophenmethyl methacrylate)

Ligia Gargallo; Maria Inés Muñoz; Deodato Radié

doi:10.1016/0032-3861(86)90044-3

Synthesis, solution properties and chain flexibility of poly(2-thiophenmethyl methacrylate)

Ligia Gargallo
, Maria Inés Muñoz
, Deodato Radié

Pontificia Universidad Católica de Chile

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The dilute solution behaviour of poly(2-thiophenmethyl methacrylate) (PTMM) has been studied in THF and thiophen (good solvents) and chlorobenzene (θ-solvent) at 298 K, by intrinsic viscosity, size-exclusion chromatography (SEC) and osmotic pressure measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The flexibility factor σ and the thermodynamic parameter B were calculated using the Stockmayer-Fixman equation. The results obtained are compared with those previously found for poly(benzyl methacrylate) (PBzM) and discussed in terms of the specific influence of the aromatic nature of the side group.

Original language	English
Pages (from-to)	1416-1419
Number of pages	4
Journal	Polymer
Volume	27
Issue number	9
DOIs	https://doi.org/10.1016/0032-3861(86)90044-3
State	Published - Sep 1986
Externally published	Yes

Keywords

aromatic poly(methacrylate)s
chain flexibility
poly(2-furfurylmethyl methacrylate)
poly(2-thiophenmethyl methacrylate)
poly(benzyl methacrylate)
solution properties
theta solvent

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10.1016/0032-3861(86)90044-3

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@article{4865aeab9df041bea0525650e06094ed,

title = "Synthesis, solution properties and chain flexibility of poly(2-thiophenmethyl methacrylate)",

abstract = "The dilute solution behaviour of poly(2-thiophenmethyl methacrylate) (PTMM) has been studied in THF and thiophen (good solvents) and chlorobenzene (θ-solvent) at 298 K, by intrinsic viscosity, size-exclusion chromatography (SEC) and osmotic pressure measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The flexibility factor σ and the thermodynamic parameter B were calculated using the Stockmayer-Fixman equation. The results obtained are compared with those previously found for poly(benzyl methacrylate) (PBzM) and discussed in terms of the specific influence of the aromatic nature of the side group.",

keywords = "aromatic poly(methacrylate)s, chain flexibility, poly(2-furfurylmethyl methacrylate), poly(2-thiophenmethyl methacrylate), poly(benzyl methacrylate), solution properties, theta solvent",

author = "Ligia Gargallo and Mu{\~n}oz, \{Maria In{\'e}s\} and Deodato Radi{\'e}",

year = "1986",

month = sep,

doi = "10.1016/0032-3861(86)90044-3",

language = "English",

volume = "27",

pages = "1416--1419",

journal = "Polymer",

issn = "0032-3861",

number = "9",

}

TY - JOUR

T1 - Synthesis, solution properties and chain flexibility of poly(2-thiophenmethyl methacrylate)

AU - Gargallo, Ligia

AU - Muñoz, Maria Inés

AU - Radié, Deodato

PY - 1986/9

Y1 - 1986/9

N2 - The dilute solution behaviour of poly(2-thiophenmethyl methacrylate) (PTMM) has been studied in THF and thiophen (good solvents) and chlorobenzene (θ-solvent) at 298 K, by intrinsic viscosity, size-exclusion chromatography (SEC) and osmotic pressure measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The flexibility factor σ and the thermodynamic parameter B were calculated using the Stockmayer-Fixman equation. The results obtained are compared with those previously found for poly(benzyl methacrylate) (PBzM) and discussed in terms of the specific influence of the aromatic nature of the side group.

AB - The dilute solution behaviour of poly(2-thiophenmethyl methacrylate) (PTMM) has been studied in THF and thiophen (good solvents) and chlorobenzene (θ-solvent) at 298 K, by intrinsic viscosity, size-exclusion chromatography (SEC) and osmotic pressure measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The flexibility factor σ and the thermodynamic parameter B were calculated using the Stockmayer-Fixman equation. The results obtained are compared with those previously found for poly(benzyl methacrylate) (PBzM) and discussed in terms of the specific influence of the aromatic nature of the side group.

KW - aromatic poly(methacrylate)s

KW - chain flexibility

KW - poly(2-furfurylmethyl methacrylate)

KW - poly(2-thiophenmethyl methacrylate)

KW - poly(benzyl methacrylate)

KW - solution properties

KW - theta solvent

UR - https://www.scopus.com/pages/publications/0342830742

U2 - 10.1016/0032-3861(86)90044-3

DO - 10.1016/0032-3861(86)90044-3

M3 - Article

AN - SCOPUS:0342830742

SN - 0032-3861

VL - 27

SP - 1416

EP - 1419

JO - Polymer

JF - Polymer

IS - 9

ER -

Synthesis, solution properties and chain flexibility of poly(2-thiophenmethyl methacrylate)

Abstract

Keywords

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