Synthesis and characterization of bulky side chain methacrylate polymers

Deodato Radić; Francisco Martínez; Ligia Gargallo; Nasrollah Hamidi

doi:10.1002/pen.10401

Synthesis and characterization of bulky side chain methacrylate polymers

Deodato Radić
, Francisco Martínez
, Ligia Gargallo
, Nasrollah Hamidi

Pontificia Universidad Católica de Chile

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The synthesis, and dilute solution behavior of poly(2,4-dimethylphenyl methacrylate) (2,4DMP), poly(2,5-dimethylphenyl methacrylate) (2,5DMP), and poly(3,5-dimethylphenyl methacrylate) (3,5DMP) is described. Comparison is made with results reported for other bulky side chain polymers. The Kuhn-Mark-Houwink-Sakurada (KMHS) relationships were established. The unperturbed dimensions (r²)_o^1/2. the rigidity factor σ, the characteristic ratio C_∞ and the thermodynamic parameters were determined, using the Stockmayer-Fixman equation, from viscometric data in good solvents. The high rigidity observed for these polymers is explained assuming that these polymers behave as kinked-chains.

Original language	English
Pages (from-to)	188-193
Number of pages	6
Journal	Polymer Engineering and Science
Volume	36
Issue number	2
DOIs	https://doi.org/10.1002/pen.10401
State	Published - 1996
Externally published	Yes

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title = "Synthesis and characterization of bulky side chain methacrylate polymers",

abstract = "The synthesis, and dilute solution behavior of poly(2,4-dimethylphenyl methacrylate) (2,4DMP), poly(2,5-dimethylphenyl methacrylate) (2,5DMP), and poly(3,5-dimethylphenyl methacrylate) (3,5DMP) is described. Comparison is made with results reported for other bulky side chain polymers. The Kuhn-Mark-Houwink-Sakurada (KMHS) relationships were established. The unperturbed dimensions (r2)o1/2. the rigidity factor σ, the characteristic ratio C∞ and the thermodynamic parameters were determined, using the Stockmayer-Fixman equation, from viscometric data in good solvents. The high rigidity observed for these polymers is explained assuming that these polymers behave as kinked-chains.",

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year = "1996",

doi = "10.1002/pen.10401",

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journal = "Polymer Engineering and Science",

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TY - JOUR

T1 - Synthesis and characterization of bulky side chain methacrylate polymers

AU - Radić, Deodato

AU - Martínez, Francisco

AU - Gargallo, Ligia

AU - Hamidi, Nasrollah

PY - 1996

Y1 - 1996

N2 - The synthesis, and dilute solution behavior of poly(2,4-dimethylphenyl methacrylate) (2,4DMP), poly(2,5-dimethylphenyl methacrylate) (2,5DMP), and poly(3,5-dimethylphenyl methacrylate) (3,5DMP) is described. Comparison is made with results reported for other bulky side chain polymers. The Kuhn-Mark-Houwink-Sakurada (KMHS) relationships were established. The unperturbed dimensions (r2)o1/2. the rigidity factor σ, the characteristic ratio C∞ and the thermodynamic parameters were determined, using the Stockmayer-Fixman equation, from viscometric data in good solvents. The high rigidity observed for these polymers is explained assuming that these polymers behave as kinked-chains.

AB - The synthesis, and dilute solution behavior of poly(2,4-dimethylphenyl methacrylate) (2,4DMP), poly(2,5-dimethylphenyl methacrylate) (2,5DMP), and poly(3,5-dimethylphenyl methacrylate) (3,5DMP) is described. Comparison is made with results reported for other bulky side chain polymers. The Kuhn-Mark-Houwink-Sakurada (KMHS) relationships were established. The unperturbed dimensions (r2)o1/2. the rigidity factor σ, the characteristic ratio C∞ and the thermodynamic parameters were determined, using the Stockmayer-Fixman equation, from viscometric data in good solvents. The high rigidity observed for these polymers is explained assuming that these polymers behave as kinked-chains.

UR - https://www.scopus.com/pages/publications/0029776940

U2 - 10.1002/pen.10401

DO - 10.1002/pen.10401

M3 - Article

AN - SCOPUS:0029776940

SN - 0032-3888

VL - 36

SP - 188

EP - 193

JO - Polymer Engineering and Science

JF - Polymer Engineering and Science

IS - 2

ER -

Synthesis and characterization of bulky side chain methacrylate polymers

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