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Solvent dependent photophysical behaviour of poly(1-naphthyl methacrylate)

  • Universidad de Santiago de Chile
  • Pontificia Universidad Católica de Chile

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

The emission spectra and photophysical behaviour of poly(1-naphthyl methacrylate) singlet state were investigated in solvents of different thermodynamic character. The quantum yields of monomeric emission, the life-times of the isolated unit and the rate constants for the quenching by biacetyl were evaluated. The same measurements were carried out for the monomeric (1-naphthyl acetate) and dimeric (di-1-naphthyl glutarate) model compounds. The data allow discussion of the effects of solvent on excimer formation and intramolecular energy migration.

Original languageEnglish
Pages (from-to)373-377
Number of pages5
JournalEuropean Polymer Journal
Volume15
Issue number4
DOIs
StatePublished - 1979
Externally publishedYes

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