Solution properties of poly(thiocarbonates) containing cyclic side chains

Ligia Gargallo; Luis H. Tagle; Deodato Radic

doi:10.1002/pi.4980220308

Solution properties of poly(thiocarbonates) containing cyclic side chains

Ligia Gargallo
, Luis H. Tagle
, Deodato Radic

Pontificia Universidad Católica de Chile

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Poly(thiocarbonates) with cyclic side chains have been studied in the theta solvent 1,4-dioxane. The Mark-Houwink-Sakurada (MHS) relationships were established and the uperturbed dimensions determined. The conformational parameters were compared with those of other poly(thiocarbonates) and related polymers. It was found that the polymers containing cyclic groups present a more extended and rigid chain. A marked influence of the nature and structure of the side chain on the conformational parameters was found.

Original language	English
Pages (from-to)	227-232
Number of pages	6
Journal	British Polymer Journal
Volume	22
Issue number	3
DOIs	https://doi.org/10.1002/pi.4980220308
State	Published - 1990
Externally published	Yes

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title = "Solution properties of poly(thiocarbonates) containing cyclic side chains",

abstract = "Poly(thiocarbonates) with cyclic side chains have been studied in the theta solvent 1,4-dioxane. The Mark-Houwink-Sakurada (MHS) relationships were established and the uperturbed dimensions determined. The conformational parameters were compared with those of other poly(thiocarbonates) and related polymers. It was found that the polymers containing cyclic groups present a more extended and rigid chain. A marked influence of the nature and structure of the side chain on the conformational parameters was found.",

author = "Ligia Gargallo and Tagle, \{Luis H.\} and Deodato Radic",

year = "1990",

doi = "10.1002/pi.4980220308",

language = "English",

volume = "22",

pages = "227--232",

journal = "British Polymer Journal",

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T1 - Solution properties of poly(thiocarbonates) containing cyclic side chains

AU - Gargallo, Ligia

AU - Tagle, Luis H.

AU - Radic, Deodato

PY - 1990

Y1 - 1990

N2 - Poly(thiocarbonates) with cyclic side chains have been studied in the theta solvent 1,4-dioxane. The Mark-Houwink-Sakurada (MHS) relationships were established and the uperturbed dimensions determined. The conformational parameters were compared with those of other poly(thiocarbonates) and related polymers. It was found that the polymers containing cyclic groups present a more extended and rigid chain. A marked influence of the nature and structure of the side chain on the conformational parameters was found.

AB - Poly(thiocarbonates) with cyclic side chains have been studied in the theta solvent 1,4-dioxane. The Mark-Houwink-Sakurada (MHS) relationships were established and the uperturbed dimensions determined. The conformational parameters were compared with those of other poly(thiocarbonates) and related polymers. It was found that the polymers containing cyclic groups present a more extended and rigid chain. A marked influence of the nature and structure of the side chain on the conformational parameters was found.

UR - https://www.scopus.com/pages/publications/0025211460

U2 - 10.1002/pi.4980220308

DO - 10.1002/pi.4980220308

M3 - Article

AN - SCOPUS:0025211460

SN - 0007-1641

VL - 22

SP - 227

EP - 232

JO - British Polymer Journal

JF - British Polymer Journal

IS - 3

ER -

Solution properties of poly(thiocarbonates) containing cyclic side chains

Abstract

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