Solution properties of poly(2-selenolylmethyl methacrylate)

Ligia Gargallo; María Inés Muñoz; Fernando R. Díaz; Deodato Radić

doi:10.1016/0032-3861(88)90409-0

Solution properties of poly(2-selenolylmethyl methacrylate)

Ligia Gargallo
, María Inés Muñoz
, Fernando R. Díaz
, Deodato Radić

Pontificia Universidad Católica de Chile

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The dilute solution behaviour of poly(2-selenolylmethyl methacrylate) has been studied in THF and chlorobenzene at 298 K, by intrinsic viscosity, size-exclusion chromatography and osmotic pressure measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The conformational parameters σ and C_∞, and the thermodynamic parameters B and A₂ were calculated. The results obtained are compared and discussed with those previously found for poly(benzyl methacrylate) and poly(2-thienylmethyl methacrylate).

Original language	English
Pages (from-to)	1898-1901
Number of pages	4
Journal	Polymer
Volume	29
Issue number	10
DOIs	https://doi.org/10.1016/0032-3861(88)90409-0
State	Published - Oct 1988
Externally published	Yes

Keywords

aromaticity index
chain flexibility
hetero atom
poly(2-selenolylmethyl methacrylate)
poly(2-thienylmethyl methacrylate)
solution properties

Access to Document

10.1016/0032-3861(88)90409-0

Cite this

@article{7948f7c2946a4335b08feb65dc4a0379,

title = "Solution properties of poly(2-selenolylmethyl methacrylate)",

abstract = "The dilute solution behaviour of poly(2-selenolylmethyl methacrylate) has been studied in THF and chlorobenzene at 298 K, by intrinsic viscosity, size-exclusion chromatography and osmotic pressure measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The conformational parameters σ and C∞, and the thermodynamic parameters B and A2 were calculated. The results obtained are compared and discussed with those previously found for poly(benzyl methacrylate) and poly(2-thienylmethyl methacrylate).",

keywords = "aromaticity index, chain flexibility, hetero atom, poly(2-selenolylmethyl methacrylate), poly(2-thienylmethyl methacrylate), solution properties",

author = "Ligia Gargallo and Mu{\~n}oz, \{Mar{\'i}a In{\'e}s\} and D{\'i}az, \{Fernando R.\} and Deodato Radi{\'c}",

year = "1988",

month = oct,

doi = "10.1016/0032-3861(88)90409-0",

language = "English",

volume = "29",

pages = "1898--1901",

journal = "Polymer",

issn = "0032-3861",

number = "10",

}

TY - JOUR

T1 - Solution properties of poly(2-selenolylmethyl methacrylate)

AU - Gargallo, Ligia

AU - Muñoz, María Inés

AU - Díaz, Fernando R.

AU - Radić, Deodato

PY - 1988/10

Y1 - 1988/10

N2 - The dilute solution behaviour of poly(2-selenolylmethyl methacrylate) has been studied in THF and chlorobenzene at 298 K, by intrinsic viscosity, size-exclusion chromatography and osmotic pressure measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The conformational parameters σ and C∞, and the thermodynamic parameters B and A2 were calculated. The results obtained are compared and discussed with those previously found for poly(benzyl methacrylate) and poly(2-thienylmethyl methacrylate).

AB - The dilute solution behaviour of poly(2-selenolylmethyl methacrylate) has been studied in THF and chlorobenzene at 298 K, by intrinsic viscosity, size-exclusion chromatography and osmotic pressure measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The conformational parameters σ and C∞, and the thermodynamic parameters B and A2 were calculated. The results obtained are compared and discussed with those previously found for poly(benzyl methacrylate) and poly(2-thienylmethyl methacrylate).

KW - aromaticity index

KW - chain flexibility

KW - hetero atom

KW - poly(2-selenolylmethyl methacrylate)

KW - poly(2-thienylmethyl methacrylate)

KW - solution properties

UR - https://www.scopus.com/pages/publications/0024092227

U2 - 10.1016/0032-3861(88)90409-0

DO - 10.1016/0032-3861(88)90409-0

M3 - Article

AN - SCOPUS:0024092227

SN - 0032-3861

VL - 29

SP - 1898

EP - 1901

JO - Polymer

JF - Polymer

IS - 10

ER -

Solution properties of poly(2-selenolylmethyl methacrylate)

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this