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Preferential adsorption of poly(alkylphenyl methacrylate)s in tetrahydrofuran/water

  • Pontificia Universidad Católica de Chile

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The preferential adsorption in dilute solution of poly(phenyl methacrylate) and its derivatives in tetrahydrofuran/water mixtures was studied by differential refractometry and dialysis equilibrium. Relationships were found between the rigidity factor σ, the inversion composition ν2(λ = 0) and the maximum of the adsorption (λmin). The results for poly(dimethylphenyl methacrylate)s are compared with other poly(methacrylate)s and poly(styrene)s. The results are discussed in terms of the differences in the symmetry of the pendant group.

Original languageEnglish
Pages (from-to)799-802
Number of pages4
JournalEuropean Polymer Journal
Volume24
Issue number8
DOIs
StatePublished - 1988
Externally publishedYes

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