Abstract
The synthesis and the dilute solutions properties of poly(1-indanyl methacrylate) (P1-IM) in THF and 1-4 dioxane at 298 K (Θ-solvent) were studied by viscosity, classical light scattering and size exclusion chromatography (SEC) measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established in the solvents studied. The unperturbed dimensions were determined by using the Stockmayer-Fixman extrapolation. From these results, the rigidity parameter σ was determined. The results show that the rigidity of P1-IM is higher than that of poly(5-indanyl methacrylate). The influence of the nature of the spacer group methylene or cyclic group is discussed and also compared with previous results found for another aromatic poly(methacrylates) series.
| Original language | English |
|---|---|
| Pages (from-to) | 31-38 |
| Number of pages | 8 |
| Journal | International Journal of Polymer Analysis and Characterization |
| Volume | 4 |
| Issue number | 1 |
| DOIs | |
| State | Published - 1997 |
| Externally published | Yes |
Keywords
- Light scattering
- Poly(1-indanyl methacrylate)
- SEC
- Solution properties
- Unperturbed dimensions
- Viscosity
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