Polymer cosolvent system-II. Preferential adsorption of binary solvent acetone/cyclohexane by poly(p-tert-butylphenyl methacrylate)

L. Gargallo; D. Radic; I. A. Katime

doi:10.1016/0014-3057(81)90150-6

Polymer cosolvent system-II. Preferential adsorption of binary solvent acetone/cyclohexane by poly(p-tert-butylphenyl methacrylate)

L. Gargallo
, D. Radic
, I. A. Katime

Pontificia Universidad Católica de Chile
University of the Basque Country

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The cosolvent system poly(p-tert butylphenyl methacrylate) (3)/acetone(1)/cyclohexane (2) has been studied at 298 K by light scattering, refractive index increment of dialysis equilibrium and viscometry. The preferential adsorption coefficient, λ*, for the whole composition range of the binary mixture acetone (1)/cyclohexane(2) has been determined. The values have been compared with the theoretically calculated values. The results indicate that in this system it is necessary to take into account the tertiary interaction parameters χ₁₂₃, χ₁₂₂ and χ₂₃₃.

Original language	English
Pages (from-to)	439-441
Number of pages	3
Journal	European Polymer Journal
Volume	17
Issue number	4
DOIs	https://doi.org/10.1016/0014-3057(81)90150-6
State	Published - 1981
Externally published	Yes

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title = "Polymer cosolvent system-II. Preferential adsorption of binary solvent acetone/cyclohexane by poly(p-tert-butylphenyl methacrylate)",

abstract = "The cosolvent system poly(p-tert butylphenyl methacrylate) (3)/acetone(1)/cyclohexane (2) has been studied at 298 K by light scattering, refractive index increment of dialysis equilibrium and viscometry. The preferential adsorption coefficient, λ*, for the whole composition range of the binary mixture acetone (1)/cyclohexane(2) has been determined. The values have been compared with the theoretically calculated values. The results indicate that in this system it is necessary to take into account the tertiary interaction parameters χ123, χ122 and χ233.",

author = "L. Gargallo and D. Radic and Katime, \{I. A.\}",

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T1 - Polymer cosolvent system-II. Preferential adsorption of binary solvent acetone/cyclohexane by poly(p-tert-butylphenyl methacrylate)

AU - Gargallo, L.

AU - Radic, D.

AU - Katime, I. A.

PY - 1981

Y1 - 1981

N2 - The cosolvent system poly(p-tert butylphenyl methacrylate) (3)/acetone(1)/cyclohexane (2) has been studied at 298 K by light scattering, refractive index increment of dialysis equilibrium and viscometry. The preferential adsorption coefficient, λ*, for the whole composition range of the binary mixture acetone (1)/cyclohexane(2) has been determined. The values have been compared with the theoretically calculated values. The results indicate that in this system it is necessary to take into account the tertiary interaction parameters χ123, χ122 and χ233.

AB - The cosolvent system poly(p-tert butylphenyl methacrylate) (3)/acetone(1)/cyclohexane (2) has been studied at 298 K by light scattering, refractive index increment of dialysis equilibrium and viscometry. The preferential adsorption coefficient, λ*, for the whole composition range of the binary mixture acetone (1)/cyclohexane(2) has been determined. The values have been compared with the theoretically calculated values. The results indicate that in this system it is necessary to take into account the tertiary interaction parameters χ123, χ122 and χ233.

UR - https://www.scopus.com/pages/publications/4544223152

U2 - 10.1016/0014-3057(81)90150-6

DO - 10.1016/0014-3057(81)90150-6

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AN - SCOPUS:4544223152

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VL - 17

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JO - European Polymer Journal

JF - European Polymer Journal

IS - 4

ER -

Polymer cosolvent system-II. Preferential adsorption of binary solvent acetone/cyclohexane by poly(p-tert-butylphenyl methacrylate)

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