Polymer conformation and viscometric behaviour-5. Synthesis, characterization and conformational studies for poly(monobenzyl itaconate)

M. Yazdani-Pedram; L. Gargallo; D. Radić

doi:10.1016/0014-3057(85)90110-7

Polymer conformation and viscometric behaviour-5. Synthesis, characterization and conformational studies for poly(monobenzyl itaconate)

M. Yazdani-Pedram
, L. Gargallo
, D. Radić

Pontificia Universidad Católica de Chile

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The behaviour in dilute solution of poly(monobenzyl itaconate) (PMBzI) covering the range M_w = 3.1 × 10° to 19.28 × 10⁴ has been studied in THF (good solvent) and methanol (θ-solvent) at 298 K. The Kuhn-Mark-Houwink-Sakurada relations were established and the unperturbed dimensions, flexibility factor "σ" and thermodynamic parameter B were calculated using Stockmayer and Fixman equation. The results indicate that σ is similar to that for poly(mono-n.octyl itaconate) from THF solutions, but very different from that for poly(dibenzyl itaconate).

Original language	English
Pages (from-to)	707-710
Number of pages	4
Journal	European Polymer Journal
Volume	21
Issue number	8
DOIs	https://doi.org/10.1016/0014-3057(85)90110-7
State	Published - 1985
Externally published	Yes

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title = "Polymer conformation and viscometric behaviour-5. Synthesis, characterization and conformational studies for poly(monobenzyl itaconate)",

abstract = "The behaviour in dilute solution of poly(monobenzyl itaconate) (PMBzI) covering the range Mw = 3.1 {\texttimes} 10° to 19.28 {\texttimes} 104 has been studied in THF (good solvent) and methanol (θ-solvent) at 298 K. The Kuhn-Mark-Houwink-Sakurada relations were established and the unperturbed dimensions, flexibility factor {"}σ{"} and thermodynamic parameter B were calculated using Stockmayer and Fixman equation. The results indicate that σ is similar to that for poly(mono-n.octyl itaconate) from THF solutions, but very different from that for poly(dibenzyl itaconate).",

author = "M. Yazdani-Pedram and L. Gargallo and D. Radi{\'c}",

year = "1985",

doi = "10.1016/0014-3057(85)90110-7",

language = "English",

volume = "21",

pages = "707--710",

journal = "European Polymer Journal",

issn = "0014-3057",

number = "8",

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TY - JOUR

T1 - Polymer conformation and viscometric behaviour-5. Synthesis, characterization and conformational studies for poly(monobenzyl itaconate)

AU - Yazdani-Pedram, M.

AU - Gargallo, L.

AU - Radić, D.

PY - 1985

Y1 - 1985

N2 - The behaviour in dilute solution of poly(monobenzyl itaconate) (PMBzI) covering the range Mw = 3.1 × 10° to 19.28 × 104 has been studied in THF (good solvent) and methanol (θ-solvent) at 298 K. The Kuhn-Mark-Houwink-Sakurada relations were established and the unperturbed dimensions, flexibility factor "σ" and thermodynamic parameter B were calculated using Stockmayer and Fixman equation. The results indicate that σ is similar to that for poly(mono-n.octyl itaconate) from THF solutions, but very different from that for poly(dibenzyl itaconate).

AB - The behaviour in dilute solution of poly(monobenzyl itaconate) (PMBzI) covering the range Mw = 3.1 × 10° to 19.28 × 104 has been studied in THF (good solvent) and methanol (θ-solvent) at 298 K. The Kuhn-Mark-Houwink-Sakurada relations were established and the unperturbed dimensions, flexibility factor "σ" and thermodynamic parameter B were calculated using Stockmayer and Fixman equation. The results indicate that σ is similar to that for poly(mono-n.octyl itaconate) from THF solutions, but very different from that for poly(dibenzyl itaconate).

UR - https://www.scopus.com/pages/publications/3943049091

U2 - 10.1016/0014-3057(85)90110-7

DO - 10.1016/0014-3057(85)90110-7

M3 - Article

AN - SCOPUS:3943049091

SN - 0014-3057

VL - 21

SP - 707

EP - 710

JO - European Polymer Journal

JF - European Polymer Journal

IS - 8

ER -

Polymer conformation and viscometric behaviour-5. Synthesis, characterization and conformational studies for poly(monobenzyl itaconate)

Abstract

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