Copolymers of phenoxyethyl methacrylate with butyl methacrylate: Synthesis, characterization and reactivity ratios

Kottur Anver Basha; Thavikkannu Balakrishnan; Marcela Urzua; Angel Leiva; Luz Alegria; Ligia Gargallo; Deodato Radic

doi:10.1080/00914030802583759

Copolymers of phenoxyethyl methacrylate with butyl methacrylate: Synthesis, characterization and reactivity ratios

Kottur Anver Basha
, Thavikkannu Balakrishnan
, Marcela Urzua
, Angel Leiva
, Luz Alegria
, Ligia Gargallo
, Deodato Radic

C. Abdul Hakeem College
Periyar University
Universidad de Chile
Pontificia Universidad Católica de Chile

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Phenoxyethyl methacrylate (POEMA) and butyl methacrylate (BMA) were copolymerized by free-radical copolymerization using ,'-azobisisobutyronitrile (AIBN) in 2-butanone solution at 3331K. Copolymers were characterized by FTIR, 1H-NMR and 13C-NMR spectroscopic methods and by comparison of the spectra with the corresponding homopolymers. Thermogravimetric analysis of the copolymers was carried out in order to know their thermal stability. Copolymer composition was established by 1H-NMR analysis. Monomer reactivity ratios (MRR) were computed using the classical Fineman - Ross (FR) and Kelen - Tudos (KT) procedures. MRR were also estimated using a nonlinear computational fitting procedure, known as reactivity ratios error in variable model (RREVM). The mean sequence lengths of the copolymers were estimated and suggest that random copolymers were obtained.

Original language	English
Pages (from-to)	141-149
Number of pages	9
Journal	International Journal of Polymeric Materials and Polymeric Biomaterials
Volume	58
Issue number	3
DOIs	https://doi.org/10.1080/00914030802583759
State	Published - Mar 2009
Externally published	Yes

Keywords

Butyl methacrylate
Comonomer sequence
Copolymer characterization
Monomer reactivity ratios
Phenoxyethylmethacrylate

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10.1080/00914030802583759

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@article{a5c2baa0698143eaa33cdf8793579f04,

title = "Copolymers of phenoxyethyl methacrylate with butyl methacrylate: Synthesis, characterization and reactivity ratios",

abstract = "Phenoxyethyl methacrylate (POEMA) and butyl methacrylate (BMA) were copolymerized by free-radical copolymerization using ,'-azobisisobutyronitrile (AIBN) in 2-butanone solution at 3331K. Copolymers were characterized by FTIR, 1H-NMR and 13C-NMR spectroscopic methods and by comparison of the spectra with the corresponding homopolymers. Thermogravimetric analysis of the copolymers was carried out in order to know their thermal stability. Copolymer composition was established by 1H-NMR analysis. Monomer reactivity ratios (MRR) were computed using the classical Fineman - Ross (FR) and Kelen - Tudos (KT) procedures. MRR were also estimated using a nonlinear computational fitting procedure, known as reactivity ratios error in variable model (RREVM). The mean sequence lengths of the copolymers were estimated and suggest that random copolymers were obtained.",

keywords = "Butyl methacrylate, Comonomer sequence, Copolymer characterization, Monomer reactivity ratios, Phenoxyethylmethacrylate",

author = "Basha, \{Kottur Anver\} and Thavikkannu Balakrishnan and Marcela Urzua and Angel Leiva and Luz Alegria and Ligia Gargallo and Deodato Radic",

year = "2009",

month = mar,

doi = "10.1080/00914030802583759",

language = "English",

volume = "58",

pages = "141--149",

journal = "International Journal of Polymeric Materials and Polymeric Biomaterials",

issn = "0091-4037",

number = "3",

}

TY - JOUR

T1 - Copolymers of phenoxyethyl methacrylate with butyl methacrylate

T2 - Synthesis, characterization and reactivity ratios

AU - Basha, Kottur Anver

AU - Balakrishnan, Thavikkannu

AU - Urzua, Marcela

AU - Leiva, Angel

AU - Alegria, Luz

AU - Gargallo, Ligia

AU - Radic, Deodato

PY - 2009/3

Y1 - 2009/3

N2 - Phenoxyethyl methacrylate (POEMA) and butyl methacrylate (BMA) were copolymerized by free-radical copolymerization using ,'-azobisisobutyronitrile (AIBN) in 2-butanone solution at 3331K. Copolymers were characterized by FTIR, 1H-NMR and 13C-NMR spectroscopic methods and by comparison of the spectra with the corresponding homopolymers. Thermogravimetric analysis of the copolymers was carried out in order to know their thermal stability. Copolymer composition was established by 1H-NMR analysis. Monomer reactivity ratios (MRR) were computed using the classical Fineman - Ross (FR) and Kelen - Tudos (KT) procedures. MRR were also estimated using a nonlinear computational fitting procedure, known as reactivity ratios error in variable model (RREVM). The mean sequence lengths of the copolymers were estimated and suggest that random copolymers were obtained.

AB - Phenoxyethyl methacrylate (POEMA) and butyl methacrylate (BMA) were copolymerized by free-radical copolymerization using ,'-azobisisobutyronitrile (AIBN) in 2-butanone solution at 3331K. Copolymers were characterized by FTIR, 1H-NMR and 13C-NMR spectroscopic methods and by comparison of the spectra with the corresponding homopolymers. Thermogravimetric analysis of the copolymers was carried out in order to know their thermal stability. Copolymer composition was established by 1H-NMR analysis. Monomer reactivity ratios (MRR) were computed using the classical Fineman - Ross (FR) and Kelen - Tudos (KT) procedures. MRR were also estimated using a nonlinear computational fitting procedure, known as reactivity ratios error in variable model (RREVM). The mean sequence lengths of the copolymers were estimated and suggest that random copolymers were obtained.

KW - Butyl methacrylate

KW - Comonomer sequence

KW - Copolymer characterization

KW - Monomer reactivity ratios

KW - Phenoxyethylmethacrylate

UR - https://www.scopus.com/pages/publications/60749122808

U2 - 10.1080/00914030802583759

DO - 10.1080/00914030802583759

M3 - Article

AN - SCOPUS:60749122808

SN - 0091-4037

VL - 58

SP - 141

EP - 149

JO - International Journal of Polymeric Materials and Polymeric Biomaterials

JF - International Journal of Polymeric Materials and Polymeric Biomaterials

IS - 3

ER -

Copolymers of phenoxyethyl methacrylate with butyl methacrylate: Synthesis, characterization and reactivity ratios

Abstract

Keywords

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