Comparative study of localized side group in poly(2,3 and 4 methyl cyclohexyl methacrylate)s. TSDC measurements

Gustavo Domínguez-Espinosa; Maria J. Sanchis; Ricardo Díaz-Calleja; Claudia Pagueguy; Ligia Gargallo; Deodato Radic

doi:10.1016/j.polymer.2005.10.023

Comparative study of localized side group in poly(2,3 and 4 methyl cyclohexyl methacrylate)s. TSDC measurements

Gustavo Domínguez-Espinosa
, Maria J. Sanchis
, Ricardo Díaz-Calleja
, Claudia Pagueguy
, Ligia Gargallo
, Deodato Radic

Polytechnic University of Valencia
Pontificia Universidad Católica de Chile

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

By means of thermal sampling techniques, the fine structure of the γ-relaxation zone of poly(methyl cyclohexyl methacrylate)s (P2MCHMA), (P3MCHMA), (P4MCHMA) were analyzed. Results reveal that in this relaxation zone, at least two peaks are present. These peaks are attributed to the cis and trans isomers. Loss permittivity of the polymers under study in this relaxation zone has been reproduced from the partial depolarization data by using the elementary relaxation times and activation energies. Results are in relatively good agreement with the experimental data previously obtained. Molecular mechanic calculations have been carried out in order to elucidate the characteristics and molecular origin of the relaxations observed in this zone. An interpretation of the height of the peaks associated to the cis- and trans-isomer in terms of strain energy (SE) have been carried out.

Original language	English
Pages (from-to)	11351-11358
Number of pages	8
Journal	Polymer
Volume	46
Issue number	25
DOIs	https://doi.org/10.1016/j.polymer.2005.10.023
State	Published - 28 Nov 2005
Externally published	Yes

Keywords

Molecular mechanics calculations
Poly(methyl cyclohexyl methacrylate)s
Thermally stimulated depolarization currents

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10.1016/j.polymer.2005.10.023

Cite this

@article{7e67f3e61f3243aebbe9e78411b638ef,

title = "Comparative study of localized side group in poly(2,3 and 4 methyl cyclohexyl methacrylate)s. TSDC measurements",

abstract = "By means of thermal sampling techniques, the fine structure of the γ-relaxation zone of poly(methyl cyclohexyl methacrylate)s (P2MCHMA), (P3MCHMA), (P4MCHMA) were analyzed. Results reveal that in this relaxation zone, at least two peaks are present. These peaks are attributed to the cis and trans isomers. Loss permittivity of the polymers under study in this relaxation zone has been reproduced from the partial depolarization data by using the elementary relaxation times and activation energies. Results are in relatively good agreement with the experimental data previously obtained. Molecular mechanic calculations have been carried out in order to elucidate the characteristics and molecular origin of the relaxations observed in this zone. An interpretation of the height of the peaks associated to the cis- and trans-isomer in terms of strain energy (SE) have been carried out.",

keywords = "Molecular mechanics calculations, Poly(methyl cyclohexyl methacrylate)s, Thermally stimulated depolarization currents",

author = "Gustavo Dom{\'i}nguez-Espinosa and Sanchis, \{Maria J.\} and Ricardo D{\'i}az-Calleja and Claudia Pagueguy and Ligia Gargallo and Deodato Radic",

year = "2005",

month = nov,

day = "28",

doi = "10.1016/j.polymer.2005.10.023",

language = "English",

volume = "46",

pages = "11351--11358",

journal = "Polymer",

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number = "25",

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TY - JOUR

T1 - Comparative study of localized side group in poly(2,3 and 4 methyl cyclohexyl methacrylate)s. TSDC measurements

AU - Domínguez-Espinosa, Gustavo

AU - Sanchis, Maria J.

AU - Díaz-Calleja, Ricardo

AU - Pagueguy, Claudia

AU - Gargallo, Ligia

AU - Radic, Deodato

PY - 2005/11/28

Y1 - 2005/11/28

N2 - By means of thermal sampling techniques, the fine structure of the γ-relaxation zone of poly(methyl cyclohexyl methacrylate)s (P2MCHMA), (P3MCHMA), (P4MCHMA) were analyzed. Results reveal that in this relaxation zone, at least two peaks are present. These peaks are attributed to the cis and trans isomers. Loss permittivity of the polymers under study in this relaxation zone has been reproduced from the partial depolarization data by using the elementary relaxation times and activation energies. Results are in relatively good agreement with the experimental data previously obtained. Molecular mechanic calculations have been carried out in order to elucidate the characteristics and molecular origin of the relaxations observed in this zone. An interpretation of the height of the peaks associated to the cis- and trans-isomer in terms of strain energy (SE) have been carried out.

AB - By means of thermal sampling techniques, the fine structure of the γ-relaxation zone of poly(methyl cyclohexyl methacrylate)s (P2MCHMA), (P3MCHMA), (P4MCHMA) were analyzed. Results reveal that in this relaxation zone, at least two peaks are present. These peaks are attributed to the cis and trans isomers. Loss permittivity of the polymers under study in this relaxation zone has been reproduced from the partial depolarization data by using the elementary relaxation times and activation energies. Results are in relatively good agreement with the experimental data previously obtained. Molecular mechanic calculations have been carried out in order to elucidate the characteristics and molecular origin of the relaxations observed in this zone. An interpretation of the height of the peaks associated to the cis- and trans-isomer in terms of strain energy (SE) have been carried out.

KW - Molecular mechanics calculations

KW - Poly(methyl cyclohexyl methacrylate)s

KW - Thermally stimulated depolarization currents

UR - https://www.scopus.com/pages/publications/27844500219

U2 - 10.1016/j.polymer.2005.10.023

DO - 10.1016/j.polymer.2005.10.023

M3 - Article

AN - SCOPUS:27844500219

SN - 0032-3861

VL - 46

SP - 11351

EP - 11358

JO - Polymer

JF - Polymer

IS - 25

ER -

Comparative study of localized side group in poly(2,3 and 4 methyl cyclohexyl methacrylate)s. TSDC measurements

Abstract

Keywords

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